diff --git a/src/humanize/number.py b/src/humanize/number.py
index 52a5356a..3956c346 100644
--- a/src/humanize/number.py
+++ b/src/humanize/number.py
@@ -203,7 +203,45 @@ def intcomma(value: NumberOrString, ndigits: int | None = None) -> str:
     return result
 
 
-powers = [10**x for x in (3, 6, 9, 12, 15, 18, 21, 24, 27, 30, 33, 100)]
+powers = [
+    10**x
+    for x in (
+        3,
+        6,
+        9,
+        12,
+        15,
+        18,
+        21,
+        24,
+        27,
+        30,
+        33,
+        36,
+        39,
+        42,
+        45,
+        48,
+        51,
+        54,
+        57,
+        60,
+        63,
+        66,
+        69,
+        72,
+        75,
+        78,
+        81,
+        84,
+        87,
+        90,
+        93,
+        96,
+        99,
+        100,
+    )
+]
 human_powers = (
     NS_("thousand", "thousand"),
     NS_("million", "million"),
@@ -216,6 +254,28 @@ def intcomma(value: NumberOrString, ndigits: int | None = None) -> str:
     NS_("octillion", "octillion"),
     NS_("nonillion", "nonillion"),
     NS_("decillion", "decillion"),
+    NS_("undecillion", "undecillion"),
+    NS_("duodecillion", "duodecillion"),
+    NS_("tredecillion", "tredecillion"),
+    NS_("quattuordecillion", "quattuordecillion"),
+    NS_("quindecillion", "quindecillion"),
+    NS_("sexdecillion", "sexdecillion"),
+    NS_("septendecillion", "septendecillion"),
+    NS_("octodecillion", "octodecillion"),
+    NS_("novemdecillion", "novemdecillion"),
+    NS_("vigintillion", "vigintillion"),
+    NS_("unvigintillion", "unvigintillion"),
+    NS_("duovigintillion", "duovigintillion"),
+    NS_("trevigintillion", "trevigintillion"),
+    NS_("quattuorvigintillion", "quattuorvigintillion"),
+    NS_("quinvigintillion", "quinvigintillion"),
+    NS_("sexvigintillion", "sexvigintillion"),
+    NS_("septenvigintillion", "septenvigintillion"),
+    NS_("octovigintillion", "octovigintillion"),
+    NS_("novemvigintillion", "novemvigintillion"),
+    NS_("trigintillion", "trigintillion"),
+    NS_("untrigintillion", "untrigintillion"),
+    NS_("duotrigintillion", "duotrigintillion"),
     NS_("googol", "googol"),
 )
 
@@ -225,7 +285,7 @@ def intword(value: NumberOrString, format: str = "%.1f") -> str:
 
     Works best for numbers over 1 million. For example, 1_000_000 becomes "1.0 million",
     1_200_000 becomes "1.2 million" and "1_200_000_000" becomes "1.2 billion". Supports
-    up to decillion (33 digits) and googol (100 digits).
+    up to duotrigintillion (99 digits) and googol (100 digits).
 
     Examples:
         ```pycon
diff --git a/tests/test_number.py b/tests/test_number.py
index 5fb12fa6..6b532da1 100644
--- a/tests/test_number.py
+++ b/tests/test_number.py
@@ -123,9 +123,12 @@ def test_intword_powers() -> None:
         (["3500000000000000000000"], "3.5 sextillion"),
         (["8100000000000000000000000000000000"], "8.1 decillion"),
         (["-8100000000000000000000000000000000"], "-8.1 decillion"),
-        ([1_000_000_000_000_000_000_000_000_000_000_000_000], "1000.0 decillion"),
-        ([1_100_000_000_000_000_000_000_000_000_000_000_000], "1100.0 decillion"),
-        ([2_100_000_000_000_000_000_000_000_000_000_000_000], "2100.0 decillion"),
+        ([1_000_000_000_000_000_000_000_000_000_000_000_000], "1.0 undecillion"),
+        ([1_100_000_000_000_000_000_000_000_000_000_000_000], "1.1 undecillion"),
+        ([2_100_000_000_000_000_000_000_000_000_000_000_000], "2.1 undecillion"),
+        ([10**50], "100.0 quindecillion"),
+        ([10**99], "1.0 duotrigintillion"),
+        ([10**100 - 10**93], "1.0 googol"),
         ([2e100], "2.0 googol"),
         ([None], "None"),
         (["1230000", "%0.2f"], "1.23 million"),
@@ -176,16 +179,20 @@ def test_intword_rounding_rollover() -> None:
         assert humanize.intword(value) == f"1.0 {units[i]}"
         assert humanize.intword(value, "%.0f") == f"1 {units[i]}"
 
-    # The mantissa must never render at or above 1000 for values below a
-    # decillion; a bare "1000.0" is only expected in the sparse gap between
-    # decillion and googol, which has no dedicated unit.
-    for exponent in range(6, 34, 3):
+    # The mantissa must never render at or above 1000: every magnitude up to
+    # duotrigintillion (10**99) has a dedicated unit, and just below a googol
+    # the value carries to "1.0 googol".
+    for exponent in range(6, 100, 3):
         rendered = humanize.intword(10**exponent - 1)
         mantissa = float(rendered.split(" ", 1)[0])
         assert mantissa < 1000
 
-    # The documented decillion..googol gap must be left untouched.
-    assert humanize.intword(10**36) == "1000.0 decillion"
+    # The former decillion..googol gap is now named (#356): the magnitudes
+    # that used to render as huge decillion counts carry the correct unit.
+    assert humanize.intword(10**36) == "1.0 undecillion"
+    assert humanize.intword(10**50) == "100.0 quindecillion"
+    assert humanize.intword(10**99) == "1.0 duotrigintillion"
+    assert humanize.intword(10**100 - 10**93) == "1.0 googol"
     assert humanize.intword(2 * 10**100) == "2.0 googol"